Constructing an unprecedented {Mn<sup>II</sup><sub>38</sub>} matryoshka doll with a [Mn<sub>18</sub>(CO<sub>3</sub>)<sub>9</sub>] inorganic core and magnetocaloric effect
Tai‐Xue Wu, Ye Tao, Qiu-Ju He, Hai‐Ye Li, He‐Dong Bian, Fu‐Ping Huang
Abstract
An unprecedented [Mn<sub>18</sub>(CO<sub>3</sub>)<sub>9</sub>] inorganic core and [Mn<sub>20</sub>] metal–organic periphery composed the largest homometallic single-valence {Mn<sup>II</sup><sub>38</sub>} aggregate with a four-shells matryoshka doll that displays a significant magnetocaloric effect (MCE).
Topics & Concepts
ManganeseValence (chemistry)CrystallographyMagnetic refrigerationMaterials scienceMetalChemistryAnalytical Chemistry (journal)MagnetizationPhysicsMagnetic fieldMetallurgyOrganic chemistryQuantum mechanicsChromatographyMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal Complexes