Slow magnetic relaxation in a homo dinuclear Dy(<scp>iii</scp>) complex in a pentagonal bipyramidal geometry
Joydev Acharya, Naushad Ahmed, Jessica Flores González, Pawan Kumar, Olivier Cador, Saurabh Kumar Singh, Fabrice Pointillart, Vadapalli Chandrasekhar
Abstract
s. Through a combined experimental and ab initio electronic structure calculations studies we have thoroughly analysed the role of the ligand field around the Dy(iii), present in pentagonal bipyramidal geometry, in contributing to the slow relaxation of magnetization.
Topics & Concepts
Pentagonal bipyramidal molecular geometryRelaxation (psychology)Magnetic relaxationCrystallographyMagnetic fieldChemistryCoordination geometryMaterials scienceMagnetizationCrystal structurePhysicsMoleculeBiologyOrganic chemistryHydrogen bondNeuroscienceQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies