Spatial pinning of globally inert pores in a superhydrophobic hydrogen-bonded organic framework for inverse ethane/ethylene separation
Youlie Cai, Jing-Hong Li, Xiaoyan Xiao, Runzhi Wei, Rui-Biao Lin, Banglin Chen, Junkuo Gao
Abstract
. This work introduces a pivotal advancement in the precursor design strategy to precisely modulate secondary interaction mechanisms within porous organic frameworks, offering new horizons for customized pore engineering.
Topics & Concepts
Inertvan der Waals forceSorptionChemical physicsAdsorptionMaterials sciencePorosityChemical engineeringHydrogen bondNanotechnologyInert gasWork (physics)PolarHydrogenPorous mediumInverseHydrophobic effectWater vaporMetal-organic frameworkChemistryMicromodelSelectivityMoleculeChemical polarityContact angleMolecular dynamicsHydrophobePolarity (international relations)Core (optical fiber)Covalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsCarbon Dioxide Capture Technologies