A Blue-Light-Emitting 3 nm-Sized CsPbBr3 Perovskite Quantum Dot with ZnBr2 Synthesized by Room-Temperature Supersaturated Recrystallization
Dula Adugna Idosa, Mulualem Abebe, Dhakshnamoorthy Mani, Aparna Thankappan, Sabu Thomas, Fekadu Gochole Aga, Jung Yong Kim
Abstract
Recently, tuning the green emission of CsPbBr3 quantum dots (QDs) to blue through quantum size and confinement effects has received considerable attention due to its remarkable photophysical properties. However, the synthesis of such a blue-emitting QD has been challenging. Herein, supersaturated recrystallization was successfully implemented at room temperature to synthesize a broadband blue-emitting ZnBr2-doped CsPbBr3 QD with an average size of ~3 nm covering the blue spectrum. The structural and optical properties of CsPbBr3 QDs demonstrated that QD particle size may decrease by accommodating ZnBr2 dopants into the perovskite precursor solution. Energy-dispersive spectroscopy confirmed the presence of zinc ions with the QDs. This work provides a new strategy for synthesizing strongly quantum-confined QD materials for photonic devices such as light-emitting diodes and lighting.