Probing optical and magnetic properties <i>via</i> subtle stereoelectronic effects in mononuclear Dy<sup>III</sup>-complexes
Alexandros A. Kitos, Diogo A. Gálico, Niki Mavragani, Raúl Castañeda, Jani O. Moilanen, Jaclyn L. Brusso, Muralee Murugesu
Abstract
Tapping into the secondary coordination environment of mononuclear DyIII-complexes leads to drastic changes in luminescence and magnetism. Visualization of effects induced by stereoelectronics on the opto-magnetic properties was achieved through subtle modifications in the ligand framework.
Topics & Concepts
ChemistryCrystallographyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research