Polyvinylpyrrolidone as a Stabilizer in Synthesis of AgInS2 Quantum Dots
Oleg A. Korepanov, О. А. Aleksandrova, D. D. Firsov, Zamir Kalazhokov, Demid A. Kirilenko, Dmitry A. Kozodaev, Vasilii Matveev, Д. С. Мазинг, В. А. Мошников
Abstract
A synthesis protocol of polyvinylpyrrolidone-capped AgInS2 quantum dots in aqueous solution is reported. Nanoparticle morphology and chemical composition were studied by means of TEM, XRD, XPS, and FTIR. The obtained quantum dots were luminescent in the visible range. The photoluminescence intensity dependence on the polyvinylpyrrolidone amount was demonstrated. The wavelength of the emission maximum varied with changing the [Ag]:[In] molar ratio. The temperature dependence of the photoluminescence intensity of the polyvinylpyrrolidone-capped AgInS2 quantum dots was investigated within the temperature range of 11–294 K.