Heterogeneous photocatalytic synthesis of sulfenamides with carbon doped potassium poly(heptazine imide) through effective electron delocalization
Fei Yuan, Leilei Zhang, Haohao Jiang, Yannan Zhou, Hang Yin, Tianjing Zhu, Baocheng Yang, Shouren Zhang, Jun-Ying Ma, Lina Du
Abstract
A ground-breaking light-driven strategy to synthesize sulfenamides using K-PHI-C doping is proposed. C-doping can extend optical absorption range to near-infrared and create delocalized electronic density to enhance the single electron transfer step.
Topics & Concepts
ImidePhotocatalysisDopingPotassiumDelocalized electronCarbon fibersChemistryMaterials scienceElectronPhotochemistryPolymer chemistryOrganic chemistryOptoelectronicsCatalysisQuantum mechanicsPhysicsComposite materialComposite numberSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsAdvanced Photocatalysis Techniques