DMAP and PivOH-promoted amination/allenization reaction
Bo‐Sheng Zhang, Yuke Li, Xue‐Ya Gou, Zhe Zhang, Yang An, Xingang Wang, Yong‐Min Liang
Abstract
This report described the first DMAP and PivOH-promoted ortho-C-H amination and ipso-allenization reaction of iodobenzenes realized by Pd/norbornene cooperative catalysis. Based on control experiments and DFT calculations, we speculated that the three ligands have different functions and mechanism paths in the reaction.
Topics & Concepts
AminationChemistryNorborneneCatalysisReaction conditionsCombinatorial chemistryReaction mechanismOrganic chemistryPolymerizationPolymerCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsCatalytic Cross-Coupling Reactions