Adsorption of Fluorocarbons and Chlorocarbons by Highly Porous and Robust Fluorinated Zirconium Metal–Organic Frameworks
Hao Wang, Liang Yu, Yuhan Lin, Junjie Peng, Simon J. Teat, Lawrence J. Williams, Jing Li
Abstract
Fluorocarbons and chlorocarbons are common volatile organic compounds that pose serious risk to the environment and human health and therefore need to be effectively captured. Herein, we report a series of highly fluorinated metal–organic frameworks with high porosity (Brunauer–Emmett–Teller surface area ∼3000 m2/g) and stability. They show exceptionally high capacity and good recyclability toward the adsorption of fluorocarbons and chlorocarbons.
Topics & Concepts
ChemistryAdsorptionZirconiumPorosityMetal-organic frameworkOrganic chemistryInorganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsSulfur Compounds in Biology