Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(<scp>ii</scp>) single-ion magnets
Ben Zhang, Yang Zhou, Hao‐Yi Huang, Xiaole Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi‐Quan Zhang, Zhao‐Bo Hu
Abstract
The change of counter anions significantly affects the environment around Co( ii ) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
Topics & Concepts
Intramolecular forceMagnetIonAnisotropyMagnetic fieldZero (linguistics)Materials scienceTrigonal crystal systemCondensed matter physicsCrystallographyChemical physicsChemistryNuclear magnetic resonancePhysicsStereochemistryCrystal structureOpticsQuantum mechanicsOrganic chemistryPhilosophyLinguisticsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies