Luminescence detection of CH<sub>2</sub>Cl<sub>2</sub> by varying Cu⋯Cu interactions in a flexible porous coordination polymer
Weijie Zhang, Wan-Tao Chen, Chenhui Li, Wen-Zhu Sun, Jia‐Wen Ye, Ling Chen, Haiping Wang, Xiao‐Ming Chen
Abstract
A flexible Cu( i ) coordination polymer is reported as the luminescence sensor for the detection of CH 2 Cl 2 . The adsorption of guest molecules lengthens the Cu⋯Cu distance, resulting in luminescent blue shifts and higher emission energy.
Topics & Concepts
LuminescenceCoordination polymerPolymerAdsorptionMaterials scienceMoleculePorosityCopperNanotechnologyInorganic chemistryPhysical chemistryChemistryOptoelectronicsOrganic chemistryMetallurgyComposite materialMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionNanocluster Synthesis and Applications