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Elastic constants of beta tungsten thin films studied by picosecond ultrasonics and density functional theory

Akira Nagakubo, H.T. Lee, Hirotsugu Ogi, Takahiro Moriyama, Teruo Ono

2020Applied Physics Letters20 citationsDOIOpen Access PDF

Abstract

Tungsten thin films are used for various applications and sometimes exhibit an A15 structure (β-W). They have some superior properties in comparison to the bcc structure (α-W), such as a higher superconducting transition temperature and larger spin Hall angle. However, elastic constants of β-W are unclear, which restricts mechanical applications and reliable density-functional-theory calculations. In this study, we synthesized α-W, β-W, and mixed-phase W films and determined their elastic constants by picosecond ultrasonics. We also calculated the elastic constants based on density functional theory and reveal that β-W has a larger elastic anisotropy and smaller shear modulus. Our calculation further indicates a stable stacking faulted β-W, which leads to a monoclinic structure.

Topics & Concepts

Density functional theoryMaterials scienceTungstenCondensed matter physicsShear modulusElastic modulusMonoclinic crystal systemThin filmPicosecondAnisotropyCrystal structureCrystallographyChemistryNanotechnologyComposite materialComputational chemistryOpticsPhysicsMetallurgyLaserMetal and Thin Film MechanicsAdvanced materials and compositesDiamond and Carbon-based Materials Research