Co‐Substitution Engineering Boosting the Kinetics and Stablity of VO<sub>2</sub> for Zn Ion Batteries
Zihan Wang, Peng Cui, Xiaomei Wang, Mengwei Chang, Yongren Yu, Junhua You, Fang Hu, Yusheng Wu, Kai Zhu
Abstract
Abstract VO 2 is considered as one of the most likely cathode materials to be commercialized for large‐scale application in AZIBs and is at the forefront of aqueous batteries, but its lower electrical conductivity, slower Zn 2+ mobility, as well as voltage degradation and structural collapse due to vanadium solubilization have limited its further development. Herein, a Co‐substitution engineering strategy is proposed, which is introducing heteroatom Co 2+ doping substitution and oxygen vacancy substitution to stabilize structure and promote ionic/electronic conductivity, leading an enhanced Zn ion storage behavior. The Co‐substituted VO 2 (Co 0.03 V 0.97 O 2‐x , denote as O v ‐CoVO) is reported in this paper, Co‐substitution inhibits vanadium dissolution of VO 2 in AZIBs, even in the acetionitrile system. DFT calculations show that O v ‐CoVO has a more stable structure as well as a faster electronic/ionic conductivity. Consequently, the O v ‐CoVO||ZnOTF||Zn battery (aqueous) can deliver a remarkable capacity of 475 mAh g −1 at 0.2 A g −1 with 99.1% capacity retention after 200 cycles, still maintains excellent cycling stability in O v ‐CoVO||ZnTFSI||Zn (acetionitrile electrolyte) at 0.1 A g −1 . In addition, compared to VO 2 , the charge transfer resistance and Zn 2+ iffusion coefficient of O v ‐CoVO are significantly enhanced. This work broadens the scope for research cathode materials for high performance ZIBs.