Probing nearby molecular vibrations with lanthanide-doped nanocrystals
Mark J. J. Mangnus, Vincent R. M. Benning, Bettina Baumgartner, P. Tim Prins, Thomas P. van Swieten, Ayla J. H. Dekker, Alfons van Blaaderen, Bert M. Weckhuysen, Andries Meijerink, Freddy T. Rabouw
Abstract
can be explained in terms of EVET-mediated quenching that involves molecular vibrations with energies resonant with the gap between the energy levels of the lanthanide. Quenching of the near-infrared-emitting level is more complex and may involve EVET to combination-vibrations or defect-mediated quenching. EVET-mediated quenching holds promise as a mechanism to probe the local chemical environment-both for nanocrystals dispersed in a liquid and for nanocrystals exposed to gaseous molecules that adsorb onto the nanocrystal surface.
Topics & Concepts
LanthanideDopingNanocrystalMaterials scienceNanotechnologyChemistryOptoelectronicsOrganic chemistryIonLuminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsLuminescence and Fluorescent Materials