Crude oil wastewater treatment by electrocoagulation in a continuous process with polarity switch
Nasibu Samson Shonza, Domênico Andreatta, Eduardo Perini Muniz, Cleocir José Dalmaschio, Rodrigo Randow de Freitas, Paulo Sérgio da Silva Porto
Abstract
The influence of the distance between electrodes, electrical current, and flow rate of emulsified crude oil in water effluent through an electrocoagulation reactor was studied. Power switch at an interval of 30 s was used to reduce electrode passivation. The output variables were power consumption, pH, and oil removal from effluent. There was no significant change in the output variables with the working time of the reactor. The final pH was between 7.5 and 9.5 depending on the input variables. It increases with higher electrical current and tends to decrease with increased flow rate. Increasing electrical current tends to increase while increasing either distance between electrodes or the flow rate tends to reduce oil removal. Using a 2.88 L reactor, it is possible to treat 7.12 L of effluent in one hour, removing 78% of the crude oil, keeping final pH at 8.3, and this system will have an energy consumption of 21.6 kWh.