Synthesis of Poly(ionic Liquid)s-<i>block</i>-poly(methyl Methacrylate) Copolymer-Grafted Silica Particle Brushes with Enhanced CO<sub>2</sub> Permeability and Mechanical Performance
Zongyu Wang, Yangyang Wang, Jihua Chen, Mark A. Arnould, Ilja Popovs, Shannon M. Mahurin, Hao Chen, Tao Wang, Sheng Dai
Abstract
Poly(ionic liquid) (PIL)-based block copolymers are of particular interest as they combine the specific properties of PILs with the self-assembling behaviors of block copolymers, broadening the range of potential applications for PIL-based materials. In this work, three particle brushes: SiO2-g-poly(methyl methacrylate) (PMMA), SiO2-g-PIL, and SiO2-g-PMMA-b-PIL were prepared through surface-initiated atom transfer radical polymerization. Unlike the homogeneous homopolymer particle brushes, the block copolymer particle brush SiO2-g-PMMA-b-PIL exhibited a bimodal chain architecture and unique phase-separated morphology, which were confirmed by size-exclusion chromatography and transmission electron microscopy. In addition, the influence of the introduction of the PMMA segment on the gas separation and mechanical performance of the PIL-containing block copolymer particle brushes were investigated. A significant improvement of Young’s modulus was observed in the SiO2-g-PMMA-b-PIL compared to the SiO2-g-PIL bulk films; meanwhile, their gas separation performances (CO2 permeability and CO2/N2 selectivity) were the same, which demonstrates the possibility of improving the mechanical properties of PIL-based particle brushes without compromising their gas separation performance.