Self-assembly of a novel multicomponent polyoxometalate-based tetrahedral supercluster with high catalytic activity for thioether oxidation
Xiaodong Liu, Na Xu, Xiaohui Liu, Yanyan Guo, Xiuli Wang
Abstract
), respectively. To our knowledge, 1 represents the first tetrahedral supercluster containing the basket-like POM structure. Besides, macromolecule 1 exhibits high catalytic activity and reusability for the oxidation of thioethers to sulfoxides.
Topics & Concepts
PolyoxometalateSupercluster (genetic)TetrahedronThioetherCatalysisMacromoleculeSelf-assemblyChemistryCrystallographyMaterials scienceOrganic chemistryGenePhylogeneticsBiochemistryPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and Applications