Reassessing Alkyne Coupling Reactions While Studying the Electronic Properties of Diverse Pyrene Linkages at Surfaces
James Lawrence, Mohammed S. G. Mohammed, Dulce Rey, Fernando Aguilar‐Galindo, Alejandro Berdonces‐Layunta, Diego Peña, Dimas G. de Oteyza
Abstract
hydrogenation and to higher levels of cyclization, particularly with nonbenzenoid product structures. We rationalize each of the studied cases.
Topics & Concepts
AlkyneIntramolecular forceScanning tunneling microscopeHalogenCoupling reactionPyrenePhotochemistryScanning tunneling spectroscopySurface modificationChemistryCoupling (piping)MoleculeMaterials scienceChemical physicsNanotechnologyStereochemistryOrganic chemistryPhysical chemistryCatalysisMetallurgyAlkylSurface Chemistry and CatalysisMolecular Junctions and NanostructuresSurface and Thin Film Phenomena