High Seebeck coefficient thermogalvanic cells <i>via</i> the solvent-sensitive charge additivity of cobalt 1,8-diaminosarcophagine
Kristine Laws, Mark A. Buckingham, Matthew Farleigh, Michelle Ma, Leigh Aldous
Abstract
' overall complex. This work proves how the ionic charge on pendant moieties can undergo charge-additivity with the metal core to significantly boost entropically-driven processes, but only in suitably low dielectric and bulky solvents.
Topics & Concepts
ChemistryValence (chemistry)Seebeck coefficientSolventRedoxCobaltIonic bondingIonic liquidProtonationMetalElectrochemistryThermoelectric effectCharge carrierAmine gas treatingPhysical chemistryInorganic chemistryThermodynamicsMaterials scienceOrganic chemistryElectrodeCatalysisIonPhysicsOptoelectronicsIonic liquids properties and applicationsAdvanced battery technologies researchOrganic and Molecular Conductors Research