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Regulating the interface defect of TiO <sub>2</sub> /Ag <sub>2</sub> O nanoheterojunction and its effect on photogenerated carrier dynamics

Yun Zhou, Hongfu Zhu, Sichao Chen, Xiaoping Ou Yang, Lixin Liu, Yuan Wang

2021Nanotechnology14 citationsDOI

Abstract

Abstract In this paper, the defects of TiO 2 /Ag 2 O nanoheterojunctions are regulated to evaluate the effect of the interface defects on carrier trapping and recombination dynamics by time-resolved photoluminescence spectroscopy (TRPL) and time-resolved terahertz (THZ) spectroscopy. TRPL spectra reveal that interface defects can act as a recombination center and have an accelerative effect on the recombination process of photogenerated carriers under ultraviolet light. Moreover, THZ spectroscopy results demonstrate that interface defects can effectively trap electrons and expedite the Auger recombination. Furthermore, the influence of interface defects on the photocarrier dynamics of TiO 2 /Ag 2 O nanoheterojunctions was comprehensively analyzed, providing a valuable experimental reference for the regulation and application of interface defect-fabricated nanoheterojunctions.

Topics & Concepts

Materials scienceRecombinationPhotoluminescenceSpectroscopyTrappingAuger effectOptoelectronicsAuger electron spectroscopyCarrier lifetimeTerahertz radiationInterface (matter)ElectronCharge carrierAtomic physicsAugerSiliconChemistryPhysicsCapillary numberBiochemistryGeneCapillary actionEcologyQuantum mechanicsNuclear physicsBiologyComposite materialAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films