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Universal tradeoff relation between speed, uncertainty, and dissipation in nonequilibrium stationary states

Izaak Neri

2022SciPost Physics31 citationsDOIOpen Access PDF

Abstract

We derive universal thermodynamic inequalities that bound from below the moments of first-passage times of stochastic currents in nonequilibrium stationary states of Markov jump processes in the limit where the two thresholds that define the first-passage problem are large. These inequalities describe a tradeoff between speed, uncertainty, and dissipation in nonequilibrium processes, which are quantified, respectively, with the moments of the first-passage times of stochastic currents, the splitting probability of the first-passage problem, and the mean entropy production rate. Near equilibrium, the inequalities imply that mean first-passage times are lower bounded by the Van't Hoff-Arrhenius law, whereas far from thermal equilibrium the bounds describe a universal speed limit for rate processes. When the current is proportional to the stochastic entropy production, then the bounds are equalities, a remarkable property that follows from the fact that the exponentiated negative entropy production is a martingale.

Topics & Concepts

Non-equilibrium thermodynamicsEntropy productionStatistical physicsMartingale (probability theory)MathematicsBounded functionEntropy (arrow of time)DissipationEntropy rateStationary stateUpper and lower boundsMarkov processPhysicsPrinciple of maximum entropyThermodynamicsApplied mathematicsMathematical analysisJoint quantum entropyQuantum mechanicsStatisticsAdvanced Thermodynamics and Statistical Mechanicsstochastic dynamics and bifurcationStatistical Mechanics and Entropy