Synergy between dynamic covalent boronic ester and boron–nitrogen coordination: strategy for self-healing polyurethane elastomers at room temperature with unprecedented mechanical properties
Kai Song, Wujin Ye, Xingchen Gao, Huagao Fang, Yaqiong Zhang, Qi Zhang, Xueliang Li, Shanzhong Yang, Haibing Wei, Yunsheng Ding
Abstract
), respectively, owing to a synergetic quadruple dynamic mechanism. It is revealed that the B-N coordination not only facilitates the formation and dissociation of boronic ester at room temperature but also dramatically enhances the mechanical properties by the intermolecular coordinated chain crosslinking and intramolecular coordinated chain folding. Meanwhile, the B-N coordination and urethane hydrogen interaction also serve as sacrificial bonds, which rupture during stretching to dissipate energy and recover after release, leading to superior notch insensitiveness and recoverability. The SPUEs restore their mechanical robustness after self-healing at room temperature and the self-healing efficiency can be dramatically accelerated by surface wetting.