Heat‐ and Light‐Responsive Materials Through Pairing Dynamic Thiol–Michael and Coumarin Chemistry
Progyateg Chakma, Shiwanka V. Wanasinghe, Colleen Morley, Sebastian C. Francesconi, Kei Saito, Jessica L. Sparks, Dominik Konkolewicz
Abstract
Covalent adaptable networks (CANs) based on the thiol-Michael (TM) linkages can be thermal and pH responsive. Here, a new vinyl-sulfone-based thiol-Michael crosslinker is synthesized and incorporated into acrylate-based CANs to achieve stable materials with dynamic properties. Because of the reversible TM linkages, excellent temperature-responsive re-healing and malleability properties are achieved. In addition, for the first time, a photoresponsive coumarin moiety is incorporated with TM-based CANs to introduce light-mediated reconfigureability and postpolymerization crosslinking. Overall, these materials can be on demand dynamic in response to heat and light but can retain mechanical stability at ambient condition.