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A facile method for the synthesis of a sintering dense nano-grained Na<sub>3</sub>Zr<sub>2</sub>Si<sub>2</sub>PO<sub>12</sub> Na<sup>+</sup>-ion solid-state electrolyte

Guanming Yang, Yanfang Zhai, Jianyao Yao, Shufeng Song, Weiping Tang, Zhaoyin Wen, Li Lü, Ning Hu

2021Chemical Communications39 citationsDOI

Abstract

We report dense Na3Zr2Si2PO12 with an average grain size of 546 ± 58 nm and prepared by a facile method. The nano-grained Na3Zr2Si2PO12 exhibits an extremely high conductivity of 1.02 × 10-3 S cm-1 and low interfacial resistance of 35 Ω cm2 at 25 °C. Such processing facilitates the exploration of nanocrystalline conductors.

Topics & Concepts

SinteringMaterials scienceGrain sizeIonAnalytical Chemistry (journal)CrystallographyMineralogyChemistryMetallurgyOrganic chemistryChromatographyAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsThermal Expansion and Ionic Conductivity
A facile method for the synthesis of a sintering dense nano-grained Na<sub>3</sub>Zr<sub>2</sub>Si<sub>2</sub>PO<sub>12</sub> Na<sup>+</sup>-ion solid-state electrolyte | Litcius