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Structure-Guided Design of <scp>d</scp>-Galactal Derivatives with High Affinity and Selectivity for the Galectin-8 N-Terminal Domain

Mujtaba Hassan, Floriane Baussière, Samo Guzelj, Anders Sundin, M. Håkansson, Rebeka Kovačič, Hakon Leffler, Tihomir Tomašič, Marko Anderluh, Žiga Jakopin, Ulf J. Nilsson

2021ACS Medicinal Chemistry Letters14 citationsDOIOpen Access PDF

Abstract

-tetrazolium) (MTS) assay evaluation of the d-galactal-benzimidazole hybrid and an analogous galactoside derivative on a panel of cell lines with MTS assay showed no effect on cell viability up to 100 μM concentration. A subsequent functional assay using the MDA-MB-231 cell line demonstrated that the d-galactal-benzimidazole hybrid and the analogous galactoside derivative reduced the secretion of the proinflammatory cytokines interleukin-6 (IL-6) and IL-8 in a dose-dependent manner. Therefore, these compounds represent potential probes for galectin-8N pharmacology investigations and possibly promising leads for the design and synthesis of potent and selective galectin-8 inhibitors as potential antitumor and anti-inflammatory agents.

Topics & Concepts

BenzimidazoleGalectinChemistrySelectivityGlycosylStereochemistryBiochemistryCatalysisOrganic chemistryGalectins and Cancer BiologyGlycosylation and Glycoproteins ResearchToxin Mechanisms and Immunotoxins
Structure-Guided Design of <scp>d</scp>-Galactal Derivatives with High Affinity and Selectivity for the Galectin-8 N-Terminal Domain | Litcius