From supramolecular to solid state chemistry: crystal engineering of luminescent materials by trapping molecular clusters in an aluminium-based host matrix
Clément Falaise, Anton A. Ivanov, Yann Molard, Maria Amela‐Cortes, Michael A. Shestopalov, Mohamed Haouas, Emmanuel Cadot, Stéphane Cordier
Abstract
Association between molybdenum clusters and Al(<sc>iii</sc>) polycations is facilitated by γ-cyclodextrin, a natural macrocyclic polysaccharide, to form luminescent supramolecular edifices.
Topics & Concepts
Supramolecular chemistryLuminescenceCrystal engineeringSolid-stateCrystal (programming language)MolybdenumChemistryTrappingAluminiumCrystal structureMaterials scienceNanotechnologyCrystallographyInorganic chemistryOrganic chemistryPhysical chemistryBiologyOptoelectronicsComputer scienceProgramming languageEcologyPolyoxometalates: Synthesis and ApplicationsInorganic Chemistry and MaterialsMetal-Organic Frameworks: Synthesis and Applications