Innovative Bioplasticizers from Residual <i><i>Cynara cardunculus</i></i> L. Biomass-Derived Levulinic Acid and Their Environmental Impact Assessment by LCA Methodology
Chiara Ruini, Paolo Neri, Gianluca Cavalaglio, Valentina Coccia, Franco Cotana, Anna Maria Raspolli Galletti, Davide Morselli, Paola Fabbri, Anna María Ferrari, Roberto Rosa
Abstract
High Resolution Image Download MS PowerPoint Slide This work is focused on the application of Life Cycle Assessment (LCA) methodology for the quantification of the potential environmental impacts associated with the obtainment of levulinic acid from residual Cynara cardunculus L. biomass and its subsequent valorization in innovative bioplasticizers for tuning the properties as well as the processability of biopolymers. This potentially allows the production of fully biobased and biodegradable bioplastic formulations, thus addressing the issues related to the fossil origin and nonbiodegradability of conventional additives, such as phthalates. Steam explosion pretreatment was applied to the epigean residue of C. cardunculus L. followed by a microwave-assisted acid-catalyzed hydrolysis. After purification, the as-obtained levulinic acid was used to synthesize different ketal-diester derivatives through a three-step selective synthesis. The levulinic acid–base additives demonstrated remarkable plasticizing efficiency when added to biobased plastics. The LCA results were used in conjunction with those from the experimental activities to find the optimal compromise between environmental impacts and mechanical and thermal properties, induced by the bioadditives in poly(3-hydroxybutyrate), PHB biopolymer.