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Tungsten‐doped foam g‐C <sub>3</sub> N <sub>4</sub> with improved photocatalytic properties for degradation of pollutant and hydrogen evolution

Yi Zong, Zixing Peng, Qian Dong, Wanbing Hu, Dandan Yang, Qianyi Guo, Zhiwu Chen, Guoping Dong

2021Journal of the American Ceramic Society13 citationsDOI

Abstract

Abstract As a potential material applied in the photocatalytic field, graphitic carbon nitride (g‐C 3 N 4 ) has attracted extensive attention for its advantages of visible‐light response, excellent thermodynamic, and chemical stability. However, the photocatalytic performance of g‐C 3 N 4 is still limited in practical applications. Here, using a facile thermal polymerization method, unique W‐doped foam g‐C 3 N 4 was synthesized to realize enhanced photocatalytic performance for the degradation of Rhodamine B and the evolution of hydrogen. Compared with pure foam g‐C 3 N 4 , tungsten doping modified the foam g‐C 3 N 4 and efficiently improved its specific surface area, leading to enhanced photocatalytic performance. The average rate of hydrogen evolution was as high as 8818 μmol·h −1 ·g −1 , which was better than most photocatalysts. This work proposes a new effective method and idea to modify g‐C 3 N 4 for improving its photocatalytic performance.

Topics & Concepts

PhotocatalysisMaterials scienceRhodamine BDegradation (telecommunications)Chemical engineeringPolymerizationDopingTungstenSpecific surface areaGraphitic carbon nitrideHydrogenVisible spectrumNanotechnologyCatalysisComposite materialPolymerChemistryOrganic chemistryOptoelectronicsMetallurgyComputer scienceEngineeringTelecommunicationsAdvanced Photocatalysis TechniquesGa2O3 and related materialsElectronic and Structural Properties of Oxides