Fabrication and DFT Calculation of Amine-Functionalized Metal–Organic Framework as a Turn-On Fluorescence Sensor for Fe<sup>3+</sup> and Al<sup>3+</sup> Ions
Ding-Gui Cai, Cheng-Qiang Qiu, Zi-Hao Zhu, Teng‐Fei Zheng, Wen‐Juan Wei, Jing‐Lin Chen, Sui‐Jun Liu, He‐Rui Wen
Abstract
Due to their important role in biological systems, it is urgent to develop a material that can rapidly and sensitively detect the concentration of Fe3+ and Al3+ ions. In this work, a brand-new CdII-based metal–organic framework [Cd(BTBD)2(AIC)]n (JXUST-18, BTBD = 4,7-bis(1H-1,2,4-triazol-1-yl)-2,1,3-benzothiadiazole and H2AIC = 5-aminoisophthalic acid) with a 4-connected sql topology was designed and synthesized. The symmetrical CdII centers are linked by AIC2– ligands with μ3-η1:η1:η1:η1 coordination mode to form a [Cd2(COO)2] secondary building unit (SBU). The contiguous SBUs are further connected by BTBD ligands to form a two-dimensional (2D) layer structure. JXUST-18 can remain stable in aqueous solutions with pH values of 3–12 or in boiling water. Luminescent experiments suggest that JXUST-18 displays more than eightfold fluorescence enhancement in the presence of Fe3+ and Al3+ ions, and the detection limits for Fe3+ and Al3+ ions are 0.196 and 0.184 μM, respectively. Furthermore, the change in luminescence color is uncomplicatedly distinguishable with the naked eye under ultraviolet light at 365 nm. In addition, a series of devices based on JXUST-18 including fluorescence test strips, lamp beads, and composite films were developed to detect metal ions via visual changes in luminescence color. Significantly, JXUST-18 is a rare MOF-based turn-on fluorescence sensor for the detection of Fe3+ ions. The theoretical calculation suggests that the complexation of Fe3+/Al3+ ions and the −NH2 group contributes to fluorescence enhancement.