An organoselenium-catalyzed N<sup>1</sup>- and N<sup>2</sup>-selective aza-Wacker reaction of alkenes with benzotriazoles
Xin Wang, Qinlin Wang, Yanru Xue, Kai Sun, Lanlan Wu, Bing Zhang
Abstract
A novel and practical organoselenium-catalyzed, N<sup>1</sup>- and N<sup>2</sup>-selective controllable aza-Wacker reaction is realized, which provides an easy access to N<sup>1</sup>- and N<sup>2</sup>-olefinated benzotriazole derivatives.
Topics & Concepts
ChemistryCatalysisBenzotriazoleSubstrate (aquarium)Combinatorial chemistryReaction mechanismWacker processOrganic chemistryMedicinal chemistryPalladiumGeologyOceanographySulfur-Based Synthesis TechniquesClick Chemistry and ApplicationsCatalytic C–H Functionalization Methods