Photochemical formation and reversible base-induced cleavage of a phosphagallene
Tobias Taeufer, Fabian Dankert, Dirk Michalik, Jola Pospech, Jonas Bresien, Christian Hering‐Junghans
Abstract
Gallaphosphenes in the spotlight: a photochemically induced PMe 3 for Cp*Ga exchange at the phosphinidenes Ar TerP gives rise to the formation of gallaphosphenes, which is fully reversible when the lights are off.
Topics & Concepts
Cleavage (geology)PhotochemistryChemistryBase (topology)Materials scienceMathematical analysisFracture (geology)MathematicsComposite materialSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistry