A novel polyoxovanadate-based Co-MOF: highly efficient and selective oxidation of a mustard gas simulant by two-site synergetic catalysis
Hong‐Rui Tian, Zhong Zhang, Shumei Liu, Shu-Mei Liu, Tian‐Yi Dang, Xiaohui Li, Ying Lü, Shu-Xia Liu, Shu-Xia Liu
Abstract
A polyoxovanadate-based cobalt organic framework (V–Co-MOF) was synthesized and it, as a heterogeneous catalyst, can catalyze the rapid selective oxidation of a mustard gas simulant to a non-toxic product by the two-site synergistic effect of V<sup>V</sup>and Co<sup>II</sup>.
Topics & Concepts
CatalysisCobaltChemistryMetal-organic frameworkHeterogeneous catalysisOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsVanadium and Halogenation ChemistryPolyoxometalates: Synthesis and Applications