Selective catalytic oxidation of humins to carboxylic acids using the H<sub>4</sub>[PVMo<sub>11</sub>O<sub>40</sub>] Keggin-type polyoxometalate enhanced by alcohol doping and solubilizer
Tobias Esser, André Wassenberg, Dorothea Voß, Jakob Albert
Abstract
Our contribution demonstrates the selective catalytic oxidation of humins to carboxylic acids using Keggin-type polyoxometalate catalysts. Remarkable CO 2 inhibiting and activity enhancing effects of additives were investigated.
Topics & Concepts
PolyoxometalateCatalysisSolubilizationDopingAlcohol oxidationAlcoholChemistryCarboxylic acidInorganic chemistryOrganic chemistryMaterials scienceBiochemistryOptoelectronicsPolyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsChemical Synthesis and Reactions