Highly sensitive and repeatable recording photopolymer for holographic data storage containing <i>N</i>-methylpyrrolidone
Junchao Jin, Po Hu, Haiyang Song, Jinhong Li, Junhui Wu, Zeyi Zeng, Qingdong Li, Li Wang, Xiao Lin, Xiaodi Tan
Abstract
), the diffraction efficiency is increased from 60% to > 80%, and volume shrinkage is decreased by a factor of 2 (from 0.4% to 0.2%). Further investigation revealed that the addition of NMP significantly reduced the molecular weight of PMMA and increased the amount of MMA residuals, while also improving the solubility of PQ molecules. More interestingly, for the first time, the NMP-PQ/PMMA material could record data information repeatedly at least 6 times. The present study elucidates that the introduction of NMP not only modulates the molecular weight of PMMA but also enables the residual monomer MMA to more easily combine with PQ to form a photoproduct for improved holographic performance.