High hydrogen release catalytic activity by quasi-MOFs prepared <i>via</i> post-synthetic pore engineering
Minoo Bagheri, Mohammad Yaser Masoomi, Esther Domı́nguez, Hermenegildo Garcı́a
Abstract
TMU-10 treated at 300 °C under air efficiently promotes H 2 generation at ambient temperature from NaBH 4 . The enhanced catalytic activity derives from a higher density of Lewis acid sites and the generation of mesoporosity.
Topics & Concepts
CatalysisLewis acids and basesHydrogenChemical engineeringMaterials scienceChemistryInorganic chemistryOrganic chemistryEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsHydrogen Storage and MaterialsCatalysis and Hydrodesulfurization Studies