Solvent effects on surface-grafted and solution-born poly[<i>N</i>-(2-hydroxypropyl)methacrylamide] during surface-initiated RAFT polymerization
Yu-Min Wang, Anna Kálosi, Yuriy Halahovets, Hynek Beneš, Andrés de los Santos Pereira, Ognen Pop‐Georgievski
Abstract
Solvent effects influence grafting density and cause discrepancy between molar mass of surface-grafted and solution-born poly[ N -(2-hydroxypropyl) methacrylamide] during surface-initiated RAFT polymerization.
Topics & Concepts
MethacrylamideRaftPolymer chemistryReversible addition−fragmentation chain-transfer polymerizationPolymerizationChain transferSolventChemistrySurface (topology)CopolymerRadical polymerizationPolymerOrganic chemistryMathematicsAcrylamideGeometryPolymer Surface Interaction StudiesAdvanced Polymer Synthesis and CharacterizationForce Microscopy Techniques and Applications