Synthesis and Structure of New Polymeric Lithium Pivalates
Ekaterina N. Zorina‐Tikhonova, Dmitriy S. Yambulatov, Mikhail A. Kiskin, Evgeniya S. Bazhina, Stanislav A. Nikolaevskii, Natalia V. Gogoleva, Irina А. Lutsenko, А.А. Sidorov, И.Л. Еременко
Abstract
Abstract Data on the synthesis and study of the crystal structure of [Li10(Piv)10(MeCN)2]n (I) and [Li6(Piv)6(MeCN)2]n (II) are presented. According to X-ray diffraction data (CIF files CCDC nos. 1957855 (I); 1955569 (II)), compounds I and II are 1D polymers composed of deca- and hexanuclear fragments, respectively, in which the lithium atoms are linked to one another by μ3- and μ4-bridging pivalate anions.
Topics & Concepts
ChemistryLithium (medication)Bridging (networking)DiffractionCrystallographyCrystal structurePolymerIonInorganic chemistryOrganic chemistryOpticsPhysicsPsychologyComputer scienceComputer networkPsychiatryCoordination Chemistry and OrganometallicsChemical Synthesis and CharacterizationPolyoxometalates: Synthesis and Applications