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Multidimensional coherent spectroscopy reveals triplet state coherences in cesium lead-halide perovskite nanocrystals

Albert Liu, Diogo B. Almeida, Luiz G. Bonato, Gabriel Nagamine, Luiz Fernando Zagonel, Ana F. Nogueira, Lázaro A. Padilha, Steven T. Cundiff

2021Science Advances58 citationsDOIOpen Access PDF

Abstract

NC ensemble. Picosecond time scale dephasing times are measured for both triplet and inter-triplet coherences, from which we infer a unique exciton fine structure level ordering composed of a dark state energetically positioned within the bright triplet manifold.

Topics & Concepts

Perovskite (structure)HalideSpectroscopyNanocrystalCaesiumTriplet stateMaterials scienceChemical physicsChemistryPhysicsAtomic physicsNanotechnologyInorganic chemistryCrystallographyExcited stateQuantum mechanicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesSolid-state spectroscopy and crystallography