Halogen bond promoted aryl migration of allylic alcohols under visible light irradiation
Keyuan Zhang, Yulong Wang, Chonglong He, Youkang Zhou, Dan‐Ning Wang, Mingyou Hu, Xin‐Hua Duan, Le Liu
Abstract
A simple and catalyst-free radical addition/1,2-aryl migration cascade process of ally alcohol driven by halogen bond was developed under visible light irradiation, featuring mild conditions, practical procedures, and broad substrate scope.
Topics & Concepts
ChemistryArylAllylic rearrangementPhotochemistryHalogenAlcoholIrradiationCatalysisSubstrate (aquarium)Visible spectrumHalogen bondCombinatorial chemistryOrganic chemistryAlkylOptoelectronicsGeologyOceanographyPhysicsNuclear physicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques