A<sub>2</sub>Zn<sub>3</sub>P<sub>4</sub>S<sub>13</sub> (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS<sub>4</sub> and P<sub>2</sub>S<sub>6</sub>
Mingze Li, Lin‐Tao Jiang, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo
Abstract
Two new IR NLO thiophosphates A 2 Zn 3 P 4 S 13 (A = Rb, Cs) feature [Zn 3 P 4 S 13 ] anionic framework and contain two types of NLO-active thiophosphate units (PS 4 and P 2 S 6 ), which to our best knowledge is unprecedented in known IR NLO thiophosphates.
Topics & Concepts
ThiophosphateNonlinear opticalInfraredMaterials scienceInfrared spectroscopyInorganic chemistryCrystallographyPhysical chemistryNonlinear systemChemistryPhysicsOpticsOrganic chemistryQuantum mechanicsCrystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography