Transition metal carbon quadruple bond: viability through single electron transmutation
Amlan J. Kalita, Shahnaz S. Rohman, Chayanika Kashyap, Sabnam S. Ullah, Ankur K. Guha
Abstract
based on high level theoretical calculations. Various bonding analyses reveal the unprecedented nature of the C[quadruple bond, length as m-dash]Fe quadruple bonding interaction. The validity of the single electron transmutation concept has been tested which fruitfully reproduces the structural and bonding similarities between the two neighbours in the periodic table.
Topics & Concepts
Nuclear transmutationValence bond theoryAtomic orbitalThree-center two-electron bondTransition metalValence (chemistry)Valence electronBondElectronCarbon fibersChemical bondMetalMetallic bondingChemistryMaterials scienceAtomic physicsChemical physicsPhysicsMetallurgyNuclear physicsOrganic chemistryFinanceComposite materialCatalysisNeutronEconomicsComposite numberSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistry