Experimental and theoretical evaluations on Oleuropein as a natural origin corrosion inhibitor for copper in acidic environment
M.A. Deyab, Q. Mohsen, Ermelinda Bloise, Maria Rosaria Lazzoi, Giuseppe Mele
Abstract
Abstract Copper corrosion in acidic cleaning solutions is a major worry for heat exchangers. Corrosion inhibitors derived from natural sources might be a viable option. The isolation of Oleuropein compound from olive leaf and investigation of its anticorrosion potential for copper in 1.0 M H 2 SO 4 solution are reported here. All experimental results from LC–MS, FT-IR, 1 H and 13 C-NMR characterizations support the molecular structure of Oleuropein. Electrochemical and gravimetric tests were used to evaluate the corrosion inhibition capabilities of Oleuropein. According to polarization investigation, Oleuropein is a mixed-type inhibitor. Oleuropein's inhibitory efficacy increases with concentration, attaining an optimum value (98.92%) at 100 mg L −1 . At high temperatures, Oleuropein can be considered an efficient inhibitor. Thermodynamic variables for the activation operation and copper dissolution were computed and addressed as well. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) examinations revealed that Oleuropein produced an outer layer on the copper surface, shielding it from severe acid damage. Quantum chemical simulations were employed to propose molecular explanations for Oleuropein's inhibitory actions.