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Rhodol‐derived turn‐on fluorescent probe for copper ions with high selectivity and sensitivity

Xiaodan Zeng, Song Gao, Cheng Jiang, Qingxia Duan, Mingshuo Ma, Zhigang Liu, Jie Chen

2021Luminescence20 citationsDOI

Abstract

Abstract A new rhodol‐derived fluorescent probe 1 with picolinate as the recognition receptor was designed and simply synthesized using a one‐step reaction. With the concentration of added Cu 2+ increases, it gradually turns pink, so the effect of naked eye detection can be achieved. The detection limit of probe 1 for Cu 2+ is 42 nM, and the linear detection range was 0–2 μM. The experimental results showed that 1 was a fluorescent probe with high selectivity, good water solubility, and high sensitivity to Cu 2+ . Probe 1 was successfully applied in cell imaging experiments and can detect the concentration of Cu 2+ in water samples. All these indicate that probe 1 has the potential to be applied to the detection of Cu 2+ concentration in the real environment.

Topics & Concepts

Detection limitFluorescenceSelectivityCopperChemistryIonNaked eyeAnalytical Chemistry (journal)Tap waterSensitivity (control systems)Linear rangeChromatographyOpticsCatalysisEnvironmental engineeringEngineeringElectronic engineeringBiochemistryOrganic chemistryPhysicsMolecular Sensors and Ion DetectionElectrochemical Analysis and ApplicationsAdvanced biosensing and bioanalysis techniques
Rhodol‐derived turn‐on fluorescent probe for copper ions with high selectivity and sensitivity | Litcius